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Issue 10, 2011
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A meta-xylenediamidemacrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

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Abstract

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1 : 1 CDCl3 : CD3OD.

Graphical abstract: A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

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Article information


Submitted
11 Feb 2011
Accepted
25 Mar 2011
First published
03 May 2011

New J. Chem., 2011,35, 2047-2053
Article type
Paper

A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

N. H. Evans, C. J. Serpell and P. D. Beer, New J. Chem., 2011, 35, 2047
DOI: 10.1039/C1NJ20109C

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