Issue 1, 2011
From the journal:

New Journal of Chemistry

Regioselective near-equatorial chlorination of Cs-C70(CF3)8†

Alexey A. Goryunkov,a   Nadezhda A. Samokhvalova,a   Pavel A. Khavrel,a   Nikita M. Belov,a   Vitaliy Yu. Markov,a   Lev N. Sidorova  and  Sergey I. Troyanov*a  

* Corresponding authors

a Chemistry Department, Moscow State University, Moscow, Russia
E-mail: stroyano@thermo.chem.msu.ru
Fax: +7 (495) 9391240
Tel: +7 (495) 9395396

Abstract

The chlorination of Cs-C70(CF3)8 by ICl occurs at near-equatorial [5,6] bond in agreement with quantum chemical predictions; structure of the synthesized Cs-C70(CF3)8Cl2 was proven by 19F NMR spectroscopy and single crystal X-ray crystallography.

Graphical abstract: Regioselective near-equatorial chlorination of Cs-C70(CF3)8

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Article information

DOI
https://doi.org/10.1039/C0NJ00591F
Article type
Letter
Submitted
28 Jul 2010
Accepted
24 Aug 2010
First published
08 Oct 2010

New J. Chem., 2011,35, 32-35

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Regioselective near-equatorial chlorination of Cs-C70(CF3)8

A. A. Goryunkov, N. A. Samokhvalova, P. A. Khavrel, N. M. Belov, V. Yu. Markov, L. N. Sidorov and S. I. Troyanov, New J. Chem., 2011, 35, 32 DOI: 10.1039/C0NJ00591F

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