Issue 29, 2011
From the journal:

Journal of Materials Chemistry

Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application†

Thomas E. Reich,a   Karl T. Jackson,a   Sa Li,a   Puru Jenaa  and  Hani M. El-Kaderi*a  

* Corresponding authors

a Department of Chemistry, Department of Physics, Virginia Commonwealth University, Richmond, VA, United States
E-mail: helkaderi@vcu.edu
Fax: +1 804 828 8599
Tel: +1 804 828 7505

Abstract

A new class of highly porous borazine-linked polymers (BLPs) has been synthesized utilizing arylamines and boron trihalides. BLPs exhibit Brunauer–Emmett–Teller (BET) surface areas in the range of 503 to 1364 m2 g−1 and store up to 1.3 wt% of hydrogen with 7.1 kJ mol−1 isosteric heat of adsorption.

Graphical abstract: Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application

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Article information

DOI
https://doi.org/10.1039/C1JM11455G
Article type
Communication
Submitted
07 Apr 2011
Accepted
02 Jun 2011
First published
22 Jun 2011

J. Mater. Chem., 2011,21, 10629-10632

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Synthesis and characterization of highly porous borazine-linked polymers and their performance in hydrogen storage application

T. E. Reich, K. T. Jackson, S. Li, P. Jena and H. M. El-Kaderi, J. Mater. Chem., 2011, 21, 10629 DOI: 10.1039/C1JM11455G

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