D-Glucosamine as an efficient ligand for the copper-catalyzed selective synthesis of anilines from aryl halides and NaN3

Krishna Gopal Thakur; Kotha Surya Srinivas; Korupalli Chiranjeevi; Govindasamy Sekar

doi:10.1039/C1GC15469A

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d-Glucosamine as an efficient ligand for the copper-catalyzed selective synthesis of anilines from aryl halides and NaN₃†

Krishna Gopal Thakur,^a Kotha Surya Srinivas,^a Korupalli Chiranjeevi^a and Govindasamy Sekar*^a

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* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Madras, Chennai, India
E-mail: gsekar@iitm.ac.in
Fax: +91 44 2257 4202
Tel: +91 44 2257 4229

Abstract

D-Glucosamine is introduced for the first time as a green ligand with copper in a coupling reaction to synthesize anilines. The reaction proceeds in a domino fashion by the in situreduction of aryl azides formed from aryl halides and NaN₃. The high water solubility of the ligand enables easy catalyst removal.

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Article information

DOI: https://doi.org/10.1039/C1GC15469A
Article type: Communication
Submitted: 27 Apr 2011
Accepted: 21 Jun 2011
First published: 14 Jul 2011

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Green Chem., 2011,13, 2326-2329

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D-Glucosamine as an efficient ligand for the copper-catalyzed selective synthesis of anilines from aryl halides and NaN₃

K. G. Thakur, K. S. Srinivas, K. Chiranjeevi and G. Sekar, Green Chem., 2011, 13, 2326 DOI: 10.1039/C1GC15469A

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