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Volume 153, 2011
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Coherent control of the motion of complex molecules and the coupling to internal state dynamics

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Abstract

We discuss coherent control of the centre of mass motion of complex molecules by de Broglie interferometry. We describe an experiment to couple the dynamics of internal state population of complex molecules to their centre of mass motion. We discuss how this can be used to probe state population and transition, especially the photo-switching of flourinated di-azobenzene molecules between their cis- and trans-configuration. We propose an experiment to photo-isomerise complex di-azobenzene molecules in the gas-phase, including the selective detection of molecules in different conformations. In addition we discuss possible ways of optimising the conformation detection through cooling, and optical techiques.

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Publication details

The article was received on 13 Apr 2011, accepted on 02 Jun 2011 and first published on 19 Aug 2011


Article type: Paper
DOI: 10.1039/C1FD00066G
Citation: Faraday Discuss., 2011,153, 237-246

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    Coherent control of the motion of complex molecules and the coupling to internal state dynamics

    P. Venn and H. Ulbricht, Faraday Discuss., 2011, 153, 237
    DOI: 10.1039/C1FD00066G

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