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Volume 153, 2011
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Femtosecond coherent control of thermal photoassociation of magnesium atoms

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We investigate femtosecond photoassociation of thermally hot atoms in the gas phase and its coherent control. In the photoassociation process, formation of a chemical bond is facilitated by light in a free-to-bound optical transition. Here, we study free-to-bound photoassociation of a diatomic molecule induced by femtosecond pulses exciting a pair of scattering atoms interacting via the van-der-Waals-type electronic ground state potential into bound levels of an electronically excited state. The thermal gas of reactants is at temperatures in the range of hundreds of degrees. Despite this incoherent initial state, rotational and vibrational coherences are observed in the probing of the created Mg2 molecules.

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Publication details

The article was received on 01 Apr 2011, accepted on 12 May 2011 and first published on 02 Sep 2011

Article type: Paper
DOI: 10.1039/C1FD00052G
Citation: Faraday Discuss., 2011,153, 383-394
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    Femtosecond coherent control of thermal photoassociation of magnesium atoms

    L. Rybak, Z. Amitay, S. Amaran, R. Kosloff, M. Tomza, R. Moszynski and C. P. Koch, Faraday Discuss., 2011, 153, 383
    DOI: 10.1039/C1FD00052G

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