Issue 46, 2011
From the journal:

Dalton Transactions

Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RO–RCM) of cyclooctene†

Santosh Kavitake,a   Manoja K. Samantaray,a   Richard Dehn,b   Stephan Deuerlein,b   Michael Limbach,bc   Jörg A. Schachner,b   Erwan Jeanneau,d   Christophe Copéret*ae  and  Chloé Thieuleux*a  

* Corresponding authors

a Université de Lyon, C2P2, UMR 5265 (CNRS -CPE Lyon Université Lyon 1), 43 Bd. du 11 Novembre 1918, Villeurbanne Cedex, France
E-mail: thieuleux@cpe.fr

b BASF SE, Basic Chemicals Research, Carl-Bosch-Strasse 38, Ludwigshafen, Germany

c CaRLa – Catalysis Research Laboratory, Im Neuenheimer Feld 584, Heidelberg, Germany

d Centre de Diffractométrie Henri Longchambon - Université Lyon 1, 43, Bd du 11 Novembre 1918, Villeurbanne, France

e ETH Zürich, Department of Chemistry, Wolfgang-Pauli-Str., 10, Zurich, Switzerland
E-mail: ccoperet@inorg.chem.ethz.ch

Abstract

Dissymmetry for selectivity: NHC ligand with two different pendant group allows the selective formation of cyclic oligomers in place of polymers opening new strategy to generate macrocycles.

Graphical abstract: Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RO–RCM) of cyclooctene

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Article information

DOI
https://doi.org/10.1039/C1DT11643F
Article type
Communication
Submitted
31 Aug 2011
Accepted
21 Sep 2011
First published
17 Oct 2011

Dalton Trans., 2011,40, 12443-12446

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Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RO–RCM) of cyclooctene

S. Kavitake, M. K. Samantaray, R. Dehn, S. Deuerlein, M. Limbach, J. A. Schachner, E. Jeanneau, C. Copéret and C. Thieuleux, Dalton Trans., 2011, 40, 12443 DOI: 10.1039/C1DT11643F

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