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Issue 46, 2011
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Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RO–RCM) of cyclooctene

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Abstract

Dissymmetry for selectivity: NHC ligand with two different pendant group allows the selective formation of cyclic oligomers in place of polymers opening new strategy to generate macrocycles.

Graphical abstract: Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RO–RCM) of cyclooctene

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Article information


Submitted
31 Aug 2011
Accepted
21 Sep 2011
First published
17 Oct 2011

Dalton Trans., 2011,40, 12443-12446
Article type
Communication

Unsymmetrical Ru-NHC catalysts: a key for the selective tandem Ring Opening–Ring Closing alkene Metathesis (RORCM) of cyclooctene

S. Kavitake, M. K. Samantaray, R. Dehn, S. Deuerlein, M. Limbach, J. A. Schachner, E. Jeanneau, C. Copéret and C. Thieuleux, Dalton Trans., 2011, 40, 12443
DOI: 10.1039/C1DT11643F

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