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Issue 46, 2011
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New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II)

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Abstract

C–Br bond activation followed by a C–C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by [upper bond 1 start]Pd(CH2CMe2-o-C[upper bond 1 end]6H4)(η4-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction.

Graphical abstract: New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II)

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Article information


Submitted
02 Aug 2011
Accepted
29 Sep 2011
First published
25 Oct 2011

Dalton Trans., 2011,40, 12450-12453
Article type
Communication

New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II)

J. Nicasio-Collazo, E. Álvarez, J. C. Alvarado-Monzón, G. Andreu-de-Riquer, J. O. C. Jimenez-Halla, L. M. De León-Rodríguez, G. Merino, U. Morales, O. Serrano and J. A. López, Dalton Trans., 2011, 40, 12450
DOI: 10.1039/C1DT11451D

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