Issue 45, 2011
From the journal:

Dalton Transactions

Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine†

Feng Li,a   Jack K. Clegg,ab   Deanna M. D'Alessandro,a   Laurence Goux-Capes,a   Natasha F. Sciortino,a   Tony D. Keenea  and  Cameron J. Kepert*a  

* Corresponding authors

a School of Chemistry, University of Sydney, Australia
E-mail: c.kepert@chem.usyd.edu.au

b Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, United Kingdom

Abstract

Three high-spin tetranuclear cobalt(II) complexes have been prepared with the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine (ppz) through metal-ion directed self-assembly. The complexes differ by the incorporation of three different coordinating anions: chloride, thiocyanide and selenocyanide. The physical properties of these complexes have been investigated in detail.

Graphical abstract: Self-assembled Co(ii) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine

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Article information

DOI
https://doi.org/10.1039/C1DT11254F
Article type
Paper
Submitted
01 Jul 2011
Accepted
11 Oct 2011
First published
21 Oct 2011

Dalton Trans., 2011,40, 12388-12393

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Self-assembled Co(II) molecular squares incorporating the bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine

F. Li, J. K. Clegg, D. M. D'Alessandro, L. Goux-Capes, N. F. Sciortino, T. D. Keene and C. J. Kepert, Dalton Trans., 2011, 40, 12388 DOI: 10.1039/C1DT11254F

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