Issue 33, 2011
From the journal:

Dalton Transactions

Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes†

Duc Hanh Nguyen,a   Jesús J. Pérez-Torrente,*a   Laura Lomba,a   M. Victoria Jiménez,a   Fernando J. Lahoza  and  Luis A. Oro*ab  

* Corresponding authors

a Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea - ICQCH, Universidad de Zaragoza-C.S.I.C., Spain
Fax: 34 976 761187
Tel: 34 976 762286

b King Fahd University of Petroleum and Minerals, KFUPM visiting Professor, Saudi Arabia
E-mail: perez@unizar.es, oro@unizar.es

Abstract

Unsaturated σ,π-cyclooctenyl and hydrido Ir(III) complexes bearing an unusual tridentate dianionic ONO pincer-type ligand have been straightforwardly obtained from 2,6-pyridinedicarboxylic acid and standard Ir(I) starting materials. These complexes efficiently catalyzed the arene C–H borylation under thermal conditions.

Graphical abstract: Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

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Article information

DOI
https://doi.org/10.1039/C1DT11046B
Article type
Paper
Submitted
06 Apr 2011
Accepted
03 Jun 2011
First published
21 Jul 2011

Dalton Trans., 2011,40, 8429-8435

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Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

D. Hanh Nguyen, J. J. Pérez-Torrente, L. Lomba, M. Victoria Jiménez, F. J. Lahoz and L. A. Oro, Dalton Trans., 2011, 40, 8429 DOI: 10.1039/C1DT11046B

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