Issue 34, 2011
From the journal:

Dalton Transactions

Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence†

Oleksandr Hietsoi,a   Alexander S. Filatov,a   Cristina Dubceaca  and  Marina A. Petrukhina*a  

* Corresponding authors

a Department of Chemistry, University at Albany, 1400 Washington Ave., Albany, NY, USA
E-mail: marina@albany.edu
Fax: +1 518-442-3462
Tel: +1 518-442-4406

Abstract

X-Ray diffraction studies of three aliphatic copper(I) carboxylates revealed a tetranuclear core structure for [Cu4(O2CCH2CH3)4] (1), [Cu4(O2CCF3)(O2CCH2CH3)3] (2), and [Cu4(O2CCF2CF3)4] (3). The effect of a stepwise increase in electrophilicity on solid-state interactions of copper(I) tetramers as well as the implications of structural variations on photoluminescent properties of the above copper(I) propionates have been discussed.

Graphical abstract: Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence

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Article information

DOI
https://doi.org/10.1039/C1DT10848D
Article type
Paper
Submitted
05 May 2011
Accepted
10 Jun 2011
First published
01 Aug 2011

Dalton Trans., 2011,40, 8598-8603

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Tetranuclear copper(I) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescence

O. Hietsoi, A. S. Filatov, C. Dubceac and M. A. Petrukhina, Dalton Trans., 2011, 40, 8598 DOI: 10.1039/C1DT10848D

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