The chemistry of hydridocarbonylferrates revisited: syntheses and structures of the new [H2Fe4(CO)12]2− and [HFe5(CO)14]3− anions, and the [Fe(DMF)4][Fe4(CO)12(μ5-η2-CO)(μ-H)]2 adduct containing an unprecedented isocarbonyl†
Abstract
The di-hydride di-anion [H2Fe4(CO)12]2− has been quantitatively obtained by protonation of the previously reported mono-hydride tri-anion [HFe4(CO)12]3− in