Capture and activation of aerial CO2 by carbamoylation of L-threonine in a Ag(I) supramolecular framework

Di Sun; Dan-Feng Wang; Na Zhang; Fu-Jing Liu; Hong-Jun Hao; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/C1DT10571J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Capture and activation of aerial CO₂ by carbamoylation of l-threonine in a Ag(i) supramolecular framework†

Di Sun,^a Dan-Feng Wang,^a Na Zhang,^a Fu-Jing Liu,^a Hong-Jun Hao,^a Rong-Bin Huang*^a and Lan-Sun Zheng^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: rbhuang@xmu.edu.cn

^b State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, China

Abstract

An ultrasonic reaction of Ag₂O, 4,4′-bipyridine (bipy) and (2S, 3R)-3-amino-2-hydroxybutanoic acid (L-Thr) gives an unexpected Ag(I) supramolecular framework, {[Ag₃(bipy)₃(cahba)]·HCO₃·10H₂O}_n (1), in which the (2S, 3R)-3-(carboxyamino)-2-hydroxybutanoic acid (H₂cahba) is a carbamate derivative of L-Thr, obtained via in situ transformation of amino group of L-Thr into carbamate by means of CO₂ uptake.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C1DT10571J
Article type: Communication
Submitted: 02 Mar 2011
Accepted: 05 Apr 2011
First published: 21 Apr 2011

Download Citation

Dalton Trans., 2011,40, 5677-5679

Permissions

Request permissions

Capture and activation of aerial CO₂ by carbamoylation of L-threonine in a Ag(I) supramolecular framework

D. Sun, D. Wang, N. Zhang, F. Liu, H. Hao, R. Huang and L. Zheng, Dalton Trans., 2011, 40, 5677 DOI: 10.1039/C1DT10571J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions