Issue 25, 2011

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

Abstract

The metal-promoted dehydrogenation of cyclic thioethers S(C5H9)(R) (R = C5H9, Ph) to give the corresponding cycloalkenes, S(C5H7)(R), using the [Rh{Ph2P(CH2)3PPh2}]+ fragment is reported.

Graphical abstract: Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

Supplementary files

Article information

Article type
Communication
Submitted
24 Mar 2011
Accepted
04 May 2011
First published
25 May 2011

Dalton Trans., 2011,40, 6626-6628

Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment

R. Dallanegra, B. S. Pilgrim, A. B. Chaplin, T. J. Donohoe and A. S. Weller, Dalton Trans., 2011, 40, 6626 DOI: 10.1039/C1DT10503E

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