Issue 22, 2011

Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

Abstract

The ZnMe complexes of bis-ferrocenyl-β-diketiminate ligands are prepared and the reactions with [Ph3C][B(C6F5)4] are found to yield the salts [H(Ph3C)C(MeC(N(C5H4)FeCp)2ZnMe] [B(C6F5)4] and [CH2[double bond, length as m-dash]C(MeC(N(C5H4)FeCp)2ZnMe][B(C6F5)4], derived from electrophilic substitution and hydride abstraction.

Graphical abstract: Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

Supplementary files

Article information

Article type
Communication
Submitted
17 Mar 2011
Accepted
06 Apr 2011
First published
05 May 2011

Dalton Trans., 2011,40, 5836-5840

Reactions of Zn bis-ferrocenyl-β-diketiminates with [Ph3C][B(C6F5)4]

L. J. E. Stanlake and D. W. Stephan, Dalton Trans., 2011, 40, 5836 DOI: 10.1039/C1DT10452G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements