Issue 24, 2011
From the journal:

Dalton Transactions

Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2− (X = Br, I)†

Maxim N. Sokolov,*ab   Maxim A. Mihailov,a   Eugenia V. Peresypkina,a   Konstantin A. Brylev,a   Noboru Kitamurac  and  Vladimir P. Fedinab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Prosp., Novosibirsk, Russia
E-mail: caesar@niic.nsc.ru
Fax: 7 3833309489
Tel: 7 3833309490

b Novosibirsk State University, 2 Ul. Pirogova, Novosibirsk, Russia

c Department of Chemistry, Faculty of Science, Hokkaido University, Japan
E-mail: kitamura@sci.hokudai.ac.jp
Tel: 81-011-7061697

Abstract

New complexes (Bu4N)2[Mo6X8(n-C3F7COO)6] (X = Br, I) display extraordinarily bright long-lived red phosphorescence both in solution and solid phases, with the highest emission quantum yields and the longest emission lifetimes among hexanuclear metal cluster complexes of Mo, W and Re, hitherto reported.

Graphical abstract: Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2− (X = Br, I)

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Article information

DOI
https://doi.org/10.1039/C1DT10376H
Article type
Communication
Submitted
04 Mar 2011
Accepted
27 Apr 2011
First published
18 May 2011

Dalton Trans., 2011,40, 6375-6377

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Highly luminescent complexes [Mo6X8(n-C3F7COO)6]2− (X = Br, I)

M. N. Sokolov, M. A. Mihailov, E. V. Peresypkina, K. A. Brylev, N. Kitamura and V. P. Fedin, Dalton Trans., 2011, 40, 6375 DOI: 10.1039/C1DT10376H

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