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Issue 35, 2011
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New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes

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Abstract

Ligand–metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp3)P pincer ligands is discussed. We demonstrated that the carbon–metal bond in these complexes may be efficiently cleaved and regenerated via1,2-addition/elimination reactions.

Graphical abstract: New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes

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Article information


Submitted
30 Jan 2011
Accepted
01 Mar 2011
First published
23 Mar 2011

Dalton Trans., 2011,40, 8760-8763
Article type
Communication

New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes

S. Musa, R. Romm, C. Azerraf, S. Kozuch and D. Gelman, Dalton Trans., 2011, 40, 8760
DOI: 10.1039/C1DT10167F

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