Issue 30, 2011
From the journal:

Dalton Transactions

Differences in the stability of zirconium(IV) complexes related to catalytic phosphine dehydrocoupling reactions†

Michael B. Ghebreab,a   David K. Newshama  and  Rory Waterman*a  

* Corresponding authors

a Department of Chemistry, University of Vermont, Cook Physical Sciences Building, Burlington, VT, USA
E-mail: rory.waterman@uvm.edu
Fax: 01 802 656-8705
Tel: 01 802 656-0278

Abstract

Relating to the catalytic dehydrocoupling of secondary phosphine substrates, zirconium phosphide complexes supported by triamidoamine and pentamethylcyclopentadienyl ligands exhibit different stability that is attributed to β-hydride elimination.

Graphical abstract: Differences in the stability of zirconium(IV) complexes related to catalytic phosphine dehydrocoupling reactions

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Article information

DOI
https://doi.org/10.1039/C1DT10105F
Article type
Communication
Submitted
18 Jan 2011
Accepted
03 Mar 2011
First published
21 Mar 2011

Dalton Trans., 2011,40, 7683-7685

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Differences in the stability of zirconium(IV) complexes related to catalytic phosphine dehydrocoupling reactions

M. B. Ghebreab, D. K. Newsham and R. Waterman, Dalton Trans., 2011, 40, 7683 DOI: 10.1039/C1DT10105F

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