Enantiopure sandwich-type nonanuclear LnIII3MnIII6 clusters

Yong Zheng; Xiang-Jian Kong; La-Sheng Long; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/C1DT10044K

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Enantiopure sandwich-type nonanuclear Ln^III₃Mn^III₆ clusters†

Yong Zheng,^a Xiang-Jian Kong,^a La-Sheng Long,*^a Rong-Bin Huang^a and Lan-Sun Zheng^a

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* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: lslong@xmu.edu.cn
Fax: +86 592 218 3047

Abstract

Three enantiopure isostructural sandwich-type clusters, Ln^III₃Mn^III₆ (Ln = Dy (1), Tb (2) and Gd (3)) have been synthesized through reactions of a chiral Schiff-base ligand ((S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid, H₃L) with manganese and lanthanide ions, showing intramolecular antiferromagnetic interaction.

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Article information

DOI: https://doi.org/10.1039/C1DT10044K
Article type: Communication
Submitted: 11 Jan 2011
Accepted: 21 Feb 2011
First published: 11 Mar 2011

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Dalton Trans., 2011,40, 4035-4037

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Enantiopure sandwich-type nonanuclear Ln^III₃Mn^III₆ clusters

Y. Zheng, X. Kong, L. Long, R. Huang and L. Zheng, Dalton Trans., 2011, 40, 4035 DOI: 10.1039/C1DT10044K

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Dalton Transactions