Issue 7, 2011
From the journal:

Dalton Transactions

Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment†

Daichi Takaki,a   Tetsuya Okayama,a   Hiroshi Shuto,a   Sawako Matsumoto,a   Yoshitaka Yamaguchi*a  and  Shinya Matsumotob  

* Corresponding authors

a Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, Yokohama, Japan
E-mail: yyama@ynu.ac.jp
Fax: +81-45-339-3932

b Course of Environmental Science, Faculty of Education and Human Science, Yokohama National University, Tokiwadai 79-2, Hodogaya-ku, Yokohama, Japan.

Abstract

Indenyl-functionalised BEt3-adduct NHCs were prepared by the reaction of imidazolium pro-ligands with LiBEt3H. This compound was converted into the indenyl-coordinate molybdenum complex dangling the NHC·BEt3 moiety as a substituent. The stepwise coordination of NHC afforded a chelate-type mononuclear complex as well as a bimetallic complex.

Graphical abstract: Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment

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Article information

DOI
https://doi.org/10.1039/C0DT01641A
Article type
Communication
Submitted
26 Nov 2010
Accepted
14 Dec 2010
First published
14 Jan 2011

Dalton Trans., 2011,40, 1445-1447

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Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment

D. Takaki, T. Okayama, H. Shuto, S. Matsumoto, Y. Yamaguchi and S. Matsumoto, Dalton Trans., 2011, 40, 1445 DOI: 10.1039/C0DT01641A

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