Step-wise synthesis of inorganic–organic hybrid based on γ-octamolybdate-based tectons†
Abstract
With the bottom-up design principle, we use metal-ions to bridge the predesigned tectons (1 [(H2L1)2(Mo8O26)]·4H2O and 3 [(H2L2)(L2)0.5(Mo8O26)0.5]·H2O) so that two higher dimensional γ-octamolybdate based inorganic–organic hybrid compounds 2 [CuI2(L1)3(Mo8O26)0.5] and 4 [Ni(L2)2(HL2)2(Mo8O26)]·4H2O are successfully obtained.