Facile synthesis of rhombic dodecahedral AgX/Ag3PO4 (X = Cl, Br, I) heterocrystals with enhanced photocatalytic properties and stabilities

Abstract

Herein, we have developed a facile and general method for the high-yield fabrication of AgX/Ag₃PO₄ (X = Cl, Br, I) core–shell heterostructures with an unusual rhombic dodecahedral morphology, which exhibit much higher photocatalytic activities, structural stabilities and photoelectric properties than pure Ag₃PO₄ crystals in environment and energy applications.