Issue 13, 2011
From the journal:

Physical Chemistry Chemical Physics

Solvent-hindered intramolecular vibrational redistribution†

John T. King,a   Jessica M. Annaa  and  Kevin J. Kubarych*a  

* Corresponding authors

a Department of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, USA
E-mail: kubarych@umich.edu

Abstract

Ultrafast two-dimensional infrared spectroscopy and molecular dynamics simulations of Mn2(CO)10 in a series of linear alcohols reveal that the rate of intramolecular vibrational redistribution among the terminal carbonyl stretches is dictated by the average number of hydrogen bonds formed between the solute and solvent. The presence of hydrogen bonds was found to hinder vibrational redistribution between eigenstates, while leaving the overall T1 relaxation rate unchanged.

Graphical abstract: Solvent-hindered intramolecular vibrational redistribution

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CP02138E
Article type
Communication
Submitted
12 Oct 2010
Accepted
07 Feb 2011
First published
28 Feb 2011

Phys. Chem. Chem. Phys., 2011,13, 5579-5583

Permissions

Request permissions

Solvent-hindered intramolecular vibrational redistribution

J. T. King, J. M. Anna and K. J. Kubarych, Phys. Chem. Chem. Phys., 2011, 13, 5579 DOI: 10.1039/C0CP02138E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements