Issue 23, 2011
From the journal:

CrystEngComm

Two unique self-penetrating metal–organic frameworks based on flexible tripodal ligands, Cu(ii) and N-containing bridging ligands†

Zheng-Bo Han,*a   Ming-Yang Zhang,a   Da-Qiang Yuan,b   Shuai Fu,a   Guo-Xin Zhanga  and  Xiao-Fang Wang*c  

* Corresponding authors

a College of Chemistry, Liaoning University, Shenyang, P.R. China
E-mail: ceshzb@lnu.edu.cn

b Department of Chemistry, Texas A & M University, PO Box 30012, College Station, TX, USA

c College of Pharm, Liaoning University, Shenyang, P.R. China
E-mail: wangxiaofang@lnu.edu.cn

Abstract

Solvothermal reaction of Cu(OAc)2·H2O, tri(2-carboxyethyl)isocyanurate (H3tci) and 4,4′-bipyridine (bpy) or 1,3-bis(4-pyridyl)propane (bpp) leads to the generation of two novel metal–organic frameworks, [Cu(Htci)(bpy)]·0.5H2O (1) and [Cu3(tci)2(bpp)2(H2O)]·3H2O (2). 1 features a 3D self-penetrating framework which results from two-fold interpenetrating 4-connected CdSO4 nets linked by carboxylate oxygen atoms of tci ligands. 2 is a 3D self-penetrating 3,4,6-connected 3-nodal net with the stoichiometry (3-c)2(4-c)(6-c) constructed by a two-fold interpenetrating (4.102)2(42.104) net connected by bpp ligands.

Graphical abstract: Two unique self-penetrating metal–organic frameworks based on flexible tripodal ligands, Cu(ii) and N-containing bridging ligands

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CE05749A
Article type
Communication
Submitted
18 Jun 2011
Accepted
22 Sep 2011
First published
12 Oct 2011

CrystEngComm, 2011,13, 6945-6949

Permissions

Request permissions

Two unique self-penetrating metal–organic frameworks based on flexible tripodal ligands, Cu(II) and N-containing bridging ligands

Z. Han, M. Zhang, D. Yuan, S. Fu, G. Zhang and X. Wang, CrystEngComm, 2011, 13, 6945 DOI: 10.1039/C1CE05749A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements