Issue 19, 2011
From the journal:

CrystEngComm

Confinement of unprecedented tetrahedral water tetramers inside 1D hydrophobic channels of metal–organic framework hosts†

Ping Yang,a   Hai-Yun Zhou,b   Kun Zhangb  and  Bao-Hui Ye*a  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: cesybh@mail.sysu.edu.cn

b Instrumental Analysis and Research Center, Sun Yat-Sen University, Guangzhou, China

Abstract

Two NbO frameworks are constructed by the reaction of Co(OAc)2·4(H2O)/Zn(OAc)2·2(H2O) with 1-(4-(1H-benzimidazol-1-yl)phenyl)butane-1,3-dione in the ratio of 1 : 2, in which they are isostructural and the NbO net exhibits a two-fold interpenetration featuring hexameric 1D channels. Theses channels are occupied by unprecedented tetrahedral tetramer water clusters.

Graphical abstract: Confinement of unprecedented tetrahedral water tetramers inside 1D hydrophobic channels of metal–organic framework hosts

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Article information

DOI
https://doi.org/10.1039/C1CE05606A
Article type
Communication
Submitted
23 May 2011
Accepted
05 Jul 2011
First published
27 Jul 2011

CrystEngComm, 2011,13, 5658-5660

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Confinement of unprecedented tetrahedral water tetramers inside 1D hydrophobic channels of metal–organic framework hosts

P. Yang, H. Zhou, K. Zhang and B. Ye, CrystEngComm, 2011, 13, 5658 DOI: 10.1039/C1CE05606A

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