Synthesis and crystal structure of tris(2,3-triphenylenedioxy)cyclotriphosphazene: a new clathration system†
Abstract
A new host compound TTPP (tris(2,3-triphenylenedioxy)cyclotriphosphazene), which is able to form a porous network, has been synthesized in five steps. When it crystallizes as a single component, TTPP exhibits a crystal structure with a monoclinic unit cell, the space groupP21/c (no. 14) and unit cell dimensions of a = 14.909(2) Å, b = 31.013(4) Å, c = 9.074(1) Å, β = 102.12(1)°.