Selective CO2 capture by a 3d–4d coordination polymer material with 1D channel†
Abstract
A porous TMCP material [Ni(cyclam)Pd(2,4-pydca)2·4H2O]n (2) was constructed from the metallotecton [Pd(2,4-Hpydca)2)] and [Ni(cyclam)](ClO4)2, and it showed highly selective capture of CO2 over N2.