Issue 10, 2011
From the journal:

CrystEngComm

Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism†

Yohei Takashima,ab   Shuhei Furukawa*bc  and  Susumu Kitagawa*abc  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

b ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park bldg #3, Shimogyo-ku, Kyoto, Japan
E-mail: shuhei.furukawa@kip.jst.go.jp
Fax: +81-75-325-3572
Tel: +81-75-322-4711

c Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan

Abstract

Based on 2,5-thiophenedicarboxylate (thdc), two isomorphic frameworks, [Zn(thdc)(dpNDI)]n, are assembled from zinc ions and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide (dpNDI). Because of the significant difference in their porous structures, these isomers show different charge-transfer interactions with electron-donating aromatic molecules.

Graphical abstract: Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

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Article information

DOI
https://doi.org/10.1039/C1CE05201B
Article type
Communication
Submitted
13 Feb 2011
Accepted
22 Mar 2011
First published
11 Apr 2011

CrystEngComm, 2011,13, 3360-3363

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Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

Y. Takashima, S. Furukawa and S. Kitagawa, CrystEngComm, 2011, 13, 3360 DOI: 10.1039/C1CE05201B

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