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Issue 10, 2011
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Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

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Abstract

Based on 2,5-thiophenedicarboxylate (thdc), two isomorphic frameworks, [Zn(thdc)(dpNDI)]n, are assembled from zinc ions and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide (dpNDI). Because of the significant difference in their porous structures, these isomers show different charge-transfer interactions with electron-donating aromatic molecules.

Graphical abstract: Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

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Publication details

The article was received on 13 Feb 2011, accepted on 22 Mar 2011 and first published on 11 Apr 2011


Article type: Communication
DOI: 10.1039/C1CE05201B
CrystEngComm, 2011,13, 3360-3363

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    Control of the charge-transfer interaction between a flexible porous coordination host and aromatic guests by framework isomerism

    Y. Takashima, S. Furukawa and S. Kitagawa, CrystEngComm, 2011, 13, 3360
    DOI: 10.1039/C1CE05201B

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