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Issue 3, 2011
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Controlled synthesis of a functionalized polytungstate ligand and a {MaMbMc(PW9)2} sandwich complex

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Abstract

The synthesis of an unprecedented vacant polytungstate ligand and its use to obtain a crystallographically characterized {MaMbMc(PW9)2}-type sandwich structure, the first example of the purposeful and controlled metal incorporation into a derivatized POM, are reported.

Graphical abstract: Controlled synthesis of a functionalized polytungstate ligand and a {MaMbMc(PW9)2} sandwich complex

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Article information


Submitted
08 Nov 2010
Accepted
11 Nov 2010
First published
26 Nov 2010

CrystEngComm, 2011,13, 738-740
Article type
Communication

Controlled synthesis of a functionalized polytungstate ligand and a {MaMbMc(PW9)2} sandwich complex

R. Cao, K. P. O'Halloran, D. A. Hillesheim, S. Lense, K. I. Hardcastle and C. L. Hill, CrystEngComm, 2011, 13, 738
DOI: 10.1039/C0CE00828A

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