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Abstract | Cited by

By imposing a two-fold interpenetration through the use of ZnSiF6 forming a linear pillar, combinations of rigid tectons bearing two divergently oriented pyridyl units interconnected either by a naphthyl or a biphenyl spacer with ZnSiF6 lead to stable porous crystalline materials.

Graphical abstract: Molecular tectonics: control of interpenetration in cuboid 3-D coordination networks

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