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Issue 6, 2011
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Molecular tectonics: control of packing of luminescent networks formed upon combining bisamidinium tectons with dicyanometallates

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Abstract

The combination of bisamidinium dicationic tectons [XX–2H+] (XX = 2–4) bearing four alkyl chains of variable lengths with linear [M(CN)2] (M = Ag or Au) anions leads to the formation of luminescent crystalline materials. The recognition mode, the connectivity patterns between cationic and anionic tectons leading to the formation of either 1- or 2-D networks as well as the packing of the latter are presented and discussed.

Graphical abstract: Molecular tectonics: control of packing of luminescent networks formed upon combining bisamidinium tectons with dicyanometallates

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Publication details

The article was received on 03 Sep 2010, accepted on 17 Nov 2010 and first published on 16 Dec 2010


Article type: Paper
DOI: 10.1039/C0CE00607F
CrystEngComm, 2011,13, 1922-1930

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    Molecular tectonics: control of packing of luminescent networks formed upon combining bisamidinium tectons with dicyanometallates

    P. Dechambenoit, S. Ferlay, N. Kyritsakas and M. W. Hosseini, CrystEngComm, 2011, 13, 1922
    DOI: 10.1039/C0CE00607F

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