Two unique 8-quinolinato (q) based one dimensional complexes [FeIIMnII(q)4·(H2O)0.25]n and [MnII(q)2]n: synthesis, structures, and magnetism

Bo Li; Jingping Zhang; Yan Zhang; Shuxin Cui; Wenliang Li; Yu Wang; Xiaoying Zhang

doi:10.1039/C0CE00488J

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Two unique 8-quinolinato (q) based one dimensional complexes [Fe^IIMn^II(q)₄·(H₂O)_0.25]_n and [Mn^II(q)₂]_n: synthesis, structures, and magnetism†

Bo Li,^a Jingping Zhang,*^a Yan Zhang,^b Shuxin Cui,^a Wenliang Li,^a Yu Wang^a and Xiaoying Zhang^a

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* Corresponding authors

^a Faculty of Chemistry, Northeast Normal University, Changchun, China
E-mail: zhangjingping66@yahoo.cn

^b Department of Physics, Peking University, Beijing, China

Abstract

Herein, we report the first incorporation of 8-hydroxyquinoline ions into hetero- and homometallic one dimensional complexes [Fe^IIMn^II(8-quinolinato)₄·(H₂O)_0.25]_n (1) and [Mn^II(8-quinolinato)₂]_n (2). Magnetic analyses of both complexes indicate antiferromagnetic interactions between the magnetic centers.

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Article information

DOI: https://doi.org/10.1039/C0CE00488J
Article type: Communication
Submitted: 03 Aug 2010
Accepted: 29 Oct 2010
First published: 15 Nov 2010

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CrystEngComm, 2011,13, 418-420

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Two unique 8-quinolinato (q) based one dimensional complexes [Fe^IIMn^II(q)₄·(H₂O)_0.25]_n and [Mn^II(q)₂]_n: synthesis, structures, and magnetism

B. Li, J. Zhang, Y. Zhang, S. Cui, W. Li, Y. Wang and X. Zhang, CrystEngComm, 2011, 13, 418 DOI: 10.1039/C0CE00488J

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