Two unique 8-quinolinato (q) based one dimensional complexes [FeIIMnII(q)4·(H2O)0.25]n and [MnII(q)2]n: synthesis, structures, and magnetism†
Abstract
Herein, we report the first incorporation of 8-hydroxyquinoline ions into hetero- and homometallic one dimensional complexes [FeIIMnII(8-quinolinato)4·(H2O)0.25]n (1) and [MnII(8-quinolinato)2]n (2). Magnetic analyses of both complexes indicate antiferromagnetic interactions between the magnetic centers.