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A new ratiometric fluorescent cyanide probe was developed based on the nucleophilic attack of CN toward the indolium group of a hybrid coumarin–hemicyanine dye, by which high selectivity as well as large emission shift could be achieved.

Graphical abstract: Ratiometric fluorescence detection of cyanide based on a hybrid coumarin–hemicyanine dye: the large emission shift and the high selectivity

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