Issue 47, 2011
From the journal:

Chemical Communications

The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures†

Julio Zukerman-Schpector,*a   Ionel Haiduc*b  and  Edward R.T. Tiekink*c  

* Corresponding authors

a Laboratório de Cristalografia, Estereodinâmica e Modelagem Molecular, Departamento de Química, Universidade Federal de São Carlos, C.P. 676, São Carlos, SP, Brazil
E-mail: julio@power.ufscar.br
Fax: +55 16 3351 8350
Tel: +55 16 3351 8208

b Facultatea de Chimie, Universitatea Babes-Bolyai, RO-400028 Cluj-Napoca, Romania
E-mail: ihaiduc@chem.ubbcluj.ro
Fax: +40 21 312 0209
Tel: +40 745 500 188

c Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
E-mail: Edward.Tiekink@gmail.com
Fax: +60 3 7967 4193
Tel: +60 3 7967 6775

Abstract

M–carbonyl(lone pair)⋯π(aryl) interactions provide stability to their transition metal crystal structures. This supramolecular synthon usually leads to zero- or one-dimensional aggregation patterns; a rare example of a three-dimensional architecture based on the M–CO(lone pair)⋯π(aryl) synthon has also been revealed.

Graphical abstract: The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures

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Article information

DOI
https://doi.org/10.1039/C1CC15579B
Article type
Communication
Submitted
09 Sep 2011
Accepted
17 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2011,47, 12682-12684

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The metal–carbonyl⋯π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures

J. Zukerman-Schpector, I. Haiduc and E. R.T. Tiekink, Chem. Commun., 2011, 47, 12682 DOI: 10.1039/C1CC15579B

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