Issue 47, 2011
From the journal:

Chemical Communications

In situ high pressure study of ZIF-8 by FTIR spectroscopy†

Yue Hu,a   Hossein Kazemian,b   Sohrab Rohani,b   Yining Huang*a  and  Yang Song*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, Ontario N6A 5B7, London, Canada
E-mail: yhuang@uwo.ca, yang.song@uwo.ca

b Department of Chemical and Biochemical Engineering, The University of Western Ontario, Ontario N6A 5B9, London, Canada

Abstract

ZIF-8 as a promising storage material was investigated at high pressures up to ∼39 GPa by in situFTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression.

Graphical abstract: In situ high pressure study of ZIF-8 by FTIR spectroscopy

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Article information

DOI
https://doi.org/10.1039/C1CC15525C
Article type
Communication
Submitted
07 Sep 2011
Accepted
13 Oct 2011
First published
31 Oct 2011

Chem. Commun., 2011,47, 12694-12696

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In situ high pressure study of ZIF-8 by FTIR spectroscopy

Y. Hu, H. Kazemian, S. Rohani, Y. Huang and Y. Song, Chem. Commun., 2011, 47, 12694 DOI: 10.1039/C1CC15525C

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