A highly efficient Brønsted acid catalyzed enantioselective Nazarov cyclization–bromination reaction has been developed. The protocol gives access to highly functionalized trans-4,5-substituted 5-bromocyclopentenone derivatives in good yields and with excellent enantioselectivities.
M. Rueping and W. Ieawsuwan, Chem. Commun., 2011, 47, 11450 DOI: 10.1039/C1CC15289K
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