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Issue 39, 2011
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Coupling of ortho-substituted aryl chlorides with bulky amides

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Abstract

Voluminous amides were coupled with deactivated, sterically hindered aryl chlorides in excellent yields providing products, which have not been efficiently accessible by transition metal catalysis so far. Application of an unsymmetric bisphosphine ligand was critical for the high catalytic activity.

Graphical abstract: Coupling of ortho-substituted aryl chlorides with bulky amides

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Supplementary files

Article information


Submitted
05 Aug 2011
Accepted
01 Sep 2011
First published
12 Sep 2011

Chem. Commun., 2011,47, 11095-11097
Article type
Communication

Coupling of ortho-substituted aryl chlorides with bulky amides

F. C. Falk, R. Fröhlich and J. Paradies, Chem. Commun., 2011, 47, 11095
DOI: 10.1039/C1CC14844C

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