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Issue 48, 2011
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pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes

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Abstract

Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.

Graphical abstract: pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes

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Article information


Submitted
03 Aug 2011
Accepted
23 Sep 2011
First published
10 Oct 2011

Chem. Commun., 2011,47, 12765-12767
Article type
Communication

pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes

C. M. Álvarez, R. Carrillo, R. García-Rodríguez and D. Miguel, Chem. Commun., 2011, 47, 12765
DOI: 10.1039/C1CC14799D

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