Issue 48, 2011
From the journal:

Chemical Communications

pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes†‡

Celedonio M. Álvarez,a   Romen Carrillo,b   Raúl García-Rodrígueza  and  Daniel Miguel*a  

* Corresponding authors

a Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, C/Prado de la Magdalena s/n, E-47071, Valladolid, Spain
E-mail: dmsj@qi.uva.es

b Laboratorio de Rayos X y Materiales Moleculares, Departamento de Física Fundamental II, Universidad de La Laguna, Avda. Astrofísico Francisco Sánchez s/n, E-38204, La Laguna, Santa Cruz de Tenerife, Spain

Abstract

Stereochemistry at the metal centre in a Re(I) complex can be modified by manipulating the pH: while acidic conditions favour a monomeric system, basic conditions induce a dimerization which concomitantly epimerizes the metal centre.

Graphical abstract: pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(i) complexes

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Article information

DOI
https://doi.org/10.1039/C1CC14799D
Article type
Communication
Submitted
03 Aug 2011
Accepted
23 Sep 2011
First published
10 Oct 2011

Chem. Commun., 2011,47, 12765-12767

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pH-driven dynamic stereoinduction: epimerization upon dimerization in rhenium(I) complexes

C. M. Álvarez, R. Carrillo, R. García-Rodríguez and D. Miguel, Chem. Commun., 2011, 47, 12765 DOI: 10.1039/C1CC14799D

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