Issue 42, 2011
From the journal:

Chemical Communications

Regio- and stereoselective synthesis of 1,4-dienes†

Shigeki Oishi,a   Keisuke Hatano,a   Akira Tsubouchia  and  Takeshi Takeda*a  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan
E-mail: takeda-t@cc.tuat.ac.jp
Fax: +81 42 388 7034
Tel: +81 42 388 7034

Abstract

Titanocene(II)-promoted cross-coupling between (Z)-alkenyl methyl sulfones and terminal allenes produced 1,4-dienes regioselectively via the formation of 2-alkylidenetitanacyclopentanes. Preferential formation of E,Z-dienes was observed in the reaction using aryl-, amino-, and phosphinylallenes.

Graphical abstract: Regio- and stereoselective synthesis of 1,4-dienes

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Article information

DOI
https://doi.org/10.1039/C1CC14765J
Article type
Communication
Submitted
02 Aug 2011
Accepted
05 Sep 2011
First published
15 Sep 2011

Chem. Commun., 2011,47, 11639-11640

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Regio- and stereoselective synthesis of 1,4-dienes

S. Oishi, K. Hatano, A. Tsubouchi and T. Takeda, Chem. Commun., 2011, 47, 11639 DOI: 10.1039/C1CC14765J

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