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Issue 38, 2011
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Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

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Abstract

Planar chiral nucleophilic catalyst Fc-PIP was employed in the kinetic resolution of bulky (hetero)arylalkyl carbinols delivering unreacted alcohols with extremely high enantiomeric excess (>99.0% ees) in ideal conversions ranging from 50.4–56.7%.

Graphical abstract: Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

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Publication details

The article was received on 27 Jul 2011, accepted on 18 Aug 2011 and first published on 05 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14591F
Citation: Chem. Commun., 2011,47, 10632-10634
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    Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

    B. Hu, M. Meng, J. S. Fossey, W. Mo, X. Hu and W. Deng, Chem. Commun., 2011, 47, 10632
    DOI: 10.1039/C1CC14591F

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