Issue 38, 2011
From the journal:

Chemical Communications

Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(ii) bis(trimethylsilyl)amide†

Richard A. Layfield,*ab   Joseph J. W. McDouall,*a   Manfred Scheer,b   Christoph Schwarzmaierb  and  Floriana Tunaa  

* Corresponding authors

a School of Chemistry, The University of Manchester, Oxford Road, Manchester, U.K
E-mail: Richard.Layfield@manchester.ac.uk

b Institut für Anorganische Chemie der Universität Regensburg, D-93040 Regensburg, Germany

Abstract

The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe3)2}2] (NHC = IPr, 2; NHC = IMes, 3) are reported.

Graphical abstract: Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(ii) bis(trimethylsilyl)amide

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Article information

DOI
https://doi.org/10.1039/C1CC14576B
Article type
Communication
Submitted
26 Jul 2011
Accepted
15 Aug 2011
First published
01 Sep 2011

Chem. Commun., 2011,47, 10623-10625

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Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl)amide

R. A. Layfield, J. J. W. McDouall, M. Scheer, C. Schwarzmaier and F. Tuna, Chem. Commun., 2011, 47, 10623 DOI: 10.1039/C1CC14576B

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