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Issue 39, 2011
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Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

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Abstract

Under UV-light irradiation, the anti-Markovnikov hydration of internal arylalkynes proceeds in the cavity of an electron-deficient coordination cage to give benzyl ketones; the reaction is triggered by cage-mediated, photo-induced electron transfer from the alkynes to the cage.

Graphical abstract: Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

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Article information


Submitted
25 Jul 2011
Accepted
26 Aug 2011
First published
09 Sep 2011

Chem. Commun., 2011,47, 10960-10962
Article type
Communication

Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

T. Murase, H. Takezawa and M. Fujita, Chem. Commun., 2011, 47, 10960
DOI: 10.1039/C1CC14523A

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