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Issue 39, 2011
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PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

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Abstract

A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.

Graphical abstract: PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

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Publication details

The article was received on 21 Jul 2011, accepted on 24 Aug 2011 and first published on 12 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14433B
Citation: Chem. Commun., 2011,47, 11104-11106
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    PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

    M. G. McLaughlin and M. J. Cook, Chem. Commun., 2011, 47, 11104
    DOI: 10.1039/C1CC14433B

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