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Issue 38, 2011

syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide

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Abstract

syn-Selective asymmetric cross-aldol reactions of aldehydes with tert-butyl glyoxylate and glyoxamide were realized by the use of an axially chiral amino sulfonamide (S)-1. The cross-aldol products obtained are densely functionalized and readily converted to synthetically useful and important chiral building blocks such as γ-lactone and γ-lactam.

Graphical abstract: syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide

Supplementary files

Article information


Submitted
19 Jul 2011
Accepted
22 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 10626-10628
Article type
Communication

syn-Selective asymmetric cross-aldol reactions between aldehydes and glyoxylic acid derivatives catalyzed by an axially chiral amino sulfonamide

T. Kano, A. Noishiki, R. Sakamoto and K. Maruoka, Chem. Commun., 2011, 47, 10626 DOI: 10.1039/C1CC14347F

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