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Issue 38, 2011
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Synthesis of the ABH rings of ecteinascidin 597 using a connective Pummerer-type cyclisation

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Abstract

A connective Pummerer-type cyclisation involving a cysteine derivative and an N-benzyl glyoxamide 3 has been applied in an asymmetric synthesis of the protected ABH rings 2 of the antitumour and antimicrobial natural product ecteinascidin 597.

Graphical abstract: Synthesis of the ABH rings of ecteinascidin 597 using a connective Pummerer-type cyclisation

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Publication details

The article was received on 04 Jul 2011, accepted on 09 Aug 2011 and first published on 24 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13992D
Citation: Chem. Commun., 2011,47, 10821-10823
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    Synthesis of the ABH rings of ecteinascidin 597 using a connective Pummerer-type cyclisation

    L. H. S. Smith, T. T. Nguyen, H. F. Sneddon and D. J. Procter, Chem. Commun., 2011, 47, 10821
    DOI: 10.1039/C1CC13992D

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