Jump to main content
Jump to site search

Issue 37, 2011
Previous Article Next Article

Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

Author affiliations

Abstract

Exposure of 3-hydroxyflavonolate complexes of the group 12 metals to UV light under aerobic conditions results in oxidative carbon–carbon bond cleavage and CO release. This reactivity is novel in that it occurs under mild reaction conditions and suggests that light-induced CO-release reactivity involving metal flavonolate species may be possible in biological systems.

Graphical abstract: Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

Back to tab navigation

Supplementary files

Article information


Submitted
02 Jul 2011
Accepted
27 Jul 2011
First published
15 Aug 2011

Chem. Commun., 2011,47, 10431-10433
Article type
Communication

Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

K. Grubel, B. J. Laughlin, T. R. Maltais, R. C. Smith, A. M. Arif and L. M. Berreau, Chem. Commun., 2011, 47, 10431
DOI: 10.1039/C1CC13961D

Social activity

Search articles by author

Spotlight

Advertisements