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Issue 38, 2011
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Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate

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Abstract

A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO3) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.

Graphical abstract: Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate

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Publication details

The article was received on 30 Jun 2011, accepted on 15 Aug 2011 and first published on 30 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13914B
Citation: Chem. Commun., 2011,47, 10644-10646
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    Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate

    M. Ratel, M. Branca, J. Breault-Turcot, S. S. Zhao, P. Chaurand, A. R. Schmitzer and J. Masson, Chem. Commun., 2011, 47, 10644
    DOI: 10.1039/C1CC13914B

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