Issue 41, 2011
From the journal:

Chemical Communications

Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene†

Ken Yamashita,a   Yuki Nagashima,a   Yoshihiko Yamamoto*a  and  Hisao Nishiyamaa  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan
E-mail: yamamoto@apchem.nagoya-u.ac.jp
Fax: +81 52 789 3209
Tel: +81 52 789 3337

Abstract

The first transfer-hydrogenative cyclization of 1,6-diynes that leads to exocyclic dienes was developed using a ruthenium catalyst and MeOH as a H2 surrogate.

Graphical abstract: Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC13744A
Article type
Communication
Submitted
23 Jun 2011
Accepted
09 Sep 2011
First published
19 Sep 2011

Chem. Commun., 2011,47, 11552-11554

Permissions

Request permissions

Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene

K. Yamashita, Y. Nagashima, Y. Yamamoto and H. Nishiyama, Chem. Commun., 2011, 47, 11552 DOI: 10.1039/C1CC13744A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements