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Issue 35, 2011
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Borido complexes via intermetallic metalloborylene transfer

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Abstract

Intermetallic borylene transfer has been applied to synthesise new borido complexes. Starting from [{(η5-C5Me5)Fe(CO)2)}(μ-B){Cr(CO)5}] (1) the borylene moiety has been transferred successfully to different transition metal fragments. In the manner described, two new compounds have been fully characterised in solution and by X-ray crystallography.

Graphical abstract: Borido complexes via intermetallic metalloborylene transfer

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Publication details

The article was received on 10 Jun 2011, accepted on 15 Jul 2011 and first published on 01 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13444B
Citation: Chem. Commun., 2011,47, 9900-9902
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    Borido complexes via intermetallic metalloborylene transfer

    H. Braunschweig, R. D. Dewhurst, K. Kraft and K. Radacki, Chem. Commun., 2011, 47, 9900
    DOI: 10.1039/C1CC13444B

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