Issue 39, 2011
From the journal:

Chemical Communications

Design and in situ synthesis of a Cu-based porous framework featuring isolated double chain magnetic character†

Chandan Dey,‡a   Raja Das,‡a   Binoy Krishna Saha,b   Pankaj Poddar*a  and  Rahul Banerjee*a  

* Corresponding authors

a Physical/Materials Chemistry Division, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008, India
E-mail: p.poddar@ncl.res.in, r.banerjee@ncl.res.in
Tel: +912025902535

b Department of Chemistry, Pondicherry University, R. V. Nagar, Kalapet, India

Abstract

A Cu-based double chain MOF was synthesized in hydrothermal conditions using an in situ ligand formation method. This double chain MOF shows temperature dependent ferromagnetic (long range ordering) and antiferromagnetic (intra double chain) coupling. The magnetic behaviour originating from the individual double chain remains almost same even after structural collapse due to the removal of guest water molecules.

Graphical abstract: Design and in situ synthesis of a Cu-based porous framework featuring isolated double chain magnetic character

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Article information

DOI
https://doi.org/10.1039/C1CC13418C
Article type
Communication
Submitted
09 Jun 2011
Accepted
22 Aug 2011
First published
12 Sep 2011

Chem. Commun., 2011,47, 11008-11010

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Design and in situ synthesis of a Cu-based porous framework featuring isolated double chain magnetic character

C. Dey, R. Das, B. Krishna Saha, P. Poddar and R. Banerjee, Chem. Commun., 2011, 47, 11008 DOI: 10.1039/C1CC13418C

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